Technically speaking, no.
Remember, when multiplying matrices, their sizes need to satisfy certain conditions.
That is, if A is m x n and B is p x q then the product AB is only defined when n=p and the resulting matrix is size m x q.
So when you look at multiplication by a scalar c to any matrix A of size m x n, the scalar product is defined. However, if you consider the 1x1 matrix consisting of c and any matrix A of size m x n, then the product cA is not necessarily defined, unless of course, m=1.
Edit: When you used the word "scalar" I took it to mean an element from your field used to /scale/ vectors from your vector space. Reread what I wrote with that in mind. If you want a better answer, ask a better question.