First, you can square the list so that you end up finding the sum of the squares. To do this, go to the lists where you entered the data. At the top of the lists, you should see L1, L2, L3, etc.
Tab over the list you want, so that the name (L1, L2, etc) is highlighted. Now, delete the numbers you see at the bottom of the screen, which should be something like:
L1 = { numbers that you've entered}
Delete those by pressing clear, and then enter L1 (or whichever list number this is in) by pressing 2nd+1 (which is L1) or 2nd+2 (which is L2), etc. After typing in the list that you've selected, press the square button, which is below the white MATH button on your calculator. Press enter. The squares should be in the list now.
For example:
You have 2, 3, and 5 entered into List 3.
Highlight the name L3. Delete the contents, which should look like: L3 = {2, 3, 5}.
Now type: L3^2
Do this by pressing 2nd+3 and then the square sign.
To find the sum of a list, click 2nd + STAT, which is the equivalene of clicking the LIST button.
Tab over to MATH. Now, go down to number 5, which is SUM(
Click it. Type in the list you want it to add by either clicking 2nd+1 (which is L1), 2nd+2 (which is L3) and so on.
You can find the standard devation by instead of clicking number 5, you can click number 7, which is stdDev(
Click it, and do the same as you would do with the SUM( by entering either L1, L2, L3, etc.