if you are using Windows, go to your Start Menu, find the "Run" command, and type in:
charmap
it should be located in C:\Windows\System32\charmap.exe
(or whatever your Windows directory is on your computer), if you do not have the Run command enabled on your Start Menu.
once you have the program open, check the "Advanced view" box, and you can search for special symbols by name.
In a sans serif font, such as Arial, a capital U will serve as a union symbol.
i like http://tlt.its.psu.edu/suggestions/international/bylanguage/mathchart.html#set
as a web resource for various math symbols.